What it is
Proton-exchange-membrane (PEM) water electrolyzers need iridium at their oxygen-evolving anode, and iridium is one of the rarest metals on Earth. Using a metal-oxide molecular self-assembly strategy, the team grew micrometre-sized, hierarchically porous iridium hydroxide particles from densely isolated IrO6H8 octahedra, with no support material. The catalyst reached a turnover frequency of 5.31 per second at 1.52 V, and the full electrolyzer held a cell voltage below 1.75 V at 4.0 A/cm^2 at an iridium loading of just 0.375 mg/cm^2.
Why it matters
Iridium supply is the hard ceiling on scaling PEM electrolysis, the cleanest route to hydrogen from renewable electricity, and its price climbed to roughly $150 per gram in 2025. Getting strong current density at low anode loading directly attacks that constraint by stretching each gram of iridium across more cells. The support-free self-assembly route is also presented as a general design principle for other high-performance membrane-electrode catalysts.
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Filed undergreen hydrogen, PEM electrolysis, iridium, electrocatalysis, oxygen evolution