What it is
Proton-exchange-membrane (PEM) water electrolyzers need iridium at their oxygen-evolving anode, and iridium is one of the rarest metals on Earth. Using a metal-oxide molecular self-assembly strategy, the team grew micrometre-sized, hierarchically porous iridium hydroxide particles from densely isolated IrO6H8 octahedra, with no support material. The catalyst reached a turnover frequency of 5.31 per second at 1.52 V, and the full electrolyzer held a cell voltage below 1.75 V at 4.0 A/cm^2 at an iridium loading of just 0.375 mg/cm^2.
Why it matters
Iridium supply is the hard ceiling on scaling PEM electrolysis, the cleanest route to hydrogen from renewable electricity. The paper gives an anode loading of about 0.4 mg of iridium per cm^2 as the kind low enough to address cost and sustainability at scale, and this electrolyzer ran at 0.375 mg/cm^2. Getting strong current density at that loading stretches each gram of iridium across more cells. The support-free self-assembly route is also presented as a general design principle for other high-performance membrane-electrode catalysts.
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Filed undergreen hydrogen, PEM electrolysis, iridium, electrocatalysis, oxygen evolution