What it is
The team built a catalyst with a cobalt-nickel alloy encapsulated in samarium-doped ceria and ran it in a solid oxide electrolysis cell converting CO2 to CO at 800 C. It reached about 90% energy efficiency with near 100% CO selectivity and a 90% single-pass yield, while lasting more than 2,000 hours at an industrial current density of 1 A per square centimeter. The encapsulated structure enhances CO2 adsorption, keeps CO adsorption moderate, and suppresses metal agglomeration, which is what usually kills these catalysts.
Why it matters
High-temperature CO2 electroreduction is one of the more industrially plausible routes to recycle carbon and store renewable energy, but prior catalysts typically fell below the mark on both efficiency and life at these conditions. Holding 90% efficiency out past 2,000 hours at a real operating current is a step-change in durability, not just activity. Simultaneously getting efficiency, selectivity, and lifetime addresses the exact trade-off that has kept this chemistry in the lab.
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Filed undercatalysis, CO2 reduction, electrolysis, carbon recycling, materials