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NotablePeer-reviewed

Homogenized chlorine distribution for >27% power conversion efficiency in perovskite solar cells

Homogenizing chlorine in perovskite films yields 27.2% certified solar-cell efficiency

ByZhuang Xiong, Qian Zhang, Kai Cai, Haitao Zhou, Qi Song, Zhaoyang Han and 2 others

Chinese Academy of Sciences · Institute of Semiconductors · University of Chinese Academy of Sciences · Soochow University

What it is

The work targets through-film inhomogeneity of chlorine, a factor the authors identify as limiting efficiency and stability, in formamidinium lead iodide films made with the common methylammonium chloride additive. Incorporating alkali metal oxalates, which thermally dissociate to release alkali metal cations that selectively bind chloride ions, homogenized the chlorine distribution, suppressed surface defects, and eliminated interfacial barriers. The resulting cells reached a certified steady-state power conversion efficiency of 27.2% and retained 86.3% of initial PCE after 1529 hours of continuous maximum power point tracking under 1 Sun.

Why it matters

Halide segregation in perovskite absorbers degrades both efficiency and operational lifetime, so controlling where chlorine sits through the film thickness addresses a mechanism, not just a symptom. The oxalate route couples a high certified efficiency with sustained stability, including an unpassivated device holding 82.8% of its original PCE under continuous operation at 85°C after 1000 hours.

Underlined numbers link to their source. Every metric and quoted figure is listed under Sources and data below.

Filed underperovskite, solar cells, photovoltaics, thin films, power conversion efficiency

Scored 2026-09-30How scoring works

The Frontier Score, in full

How this entry's score is built, term by term. Open any pillar to see each sub-metric's raw value, how it maps to 0 to 100, and the record that holds it.
Evidence 76Impact 86Novelty 48
The three pillars as one shape: a result strong on every axis fills the triangle.
How the Frontier Score is calculated for this breakthrough
TermScoreWeightPoints
EvidenceHow established and verifiable the result is.76× 0.2519.0
ImpactHow much the result matters, judged field-relative and by current momentum.86× 0.2521.5
NoveltyHow genuinely new the result is, and how fast-moving.48× 0.5024.0
Weighted pillars64.5
Frontier recency11 months since publication× 0.70
IntegrityNot retracted× 1
Frontier Score45
Confidence: Settled. Established evidence: about 399 citations across 5 independent indices.Established evidence: about 399 citations across 5 independent indices.

Every sub-metric, traced to its source

Evidence76
Evidence sub-metrics
Sub-metricRaw value0 to 100WeightPointsSource
Peer review & venueWhether the work has cleared peer review, and how selective its venue is. Peer review is necessary but not sufficient: before citations accrue, a fresh result in one of the five general flagships (Nature, Science, Cell, NEJM, the Lancet) is a stronger evidence signal than one in a selective specialist or society journal, which in turn outranks one in a legitimate but very high-volume mega-journal, and any of them outranks a preprint that has not been reviewed at all.Maps to 0 to 100: Peer-reviewed article graded by venue tier: flagship journal (Nature, Science, Cell, NEJM, the Lancet) 100; selective journal (the specialist journals of those families, JAMA, PNAS, Physical Review Letters and X) 90; high-volume mega-journal (Nature Communications, Science Advances) 78. Review 90, book 70, dataset 60, preprint 45, other 55.Peer-reviewed, flagship journal1000.3030.0OpenAlex type / primary_location / source
CorroborationIndependent corroboration that the result is real and being taken up, read as the BREADTH of agreement rather than the size of the citation pile. Counts how many of the five independent citation indices (OpenAlex, Crossref, Semantic Scholar, OpenCitations, Europe PMC) report the work at all, plus orthogonal, non-citation lines of corroboration: entry into the encyclopedia, registered clinical trials, released datasets or software, public funding on record, and technical-community discussion. Citation MAGNITUDE is deliberately judged under Impact, not here, so Evidence and Impact measure genuinely different things instead of both rewarding the same citation pile twice.Maps to 0 to 100: Starts at 28 and rises with each of the five independent citation indices that agree the work is cited (+9 each) and each orthogonal non-citation corroboration line (+6 each: Wikipedia, clinical trials, open datasets or software, public funding, community discussion). Capped at 100.5 of 5 citation indices agree730.3021.9OpenAlex, Crossref, Semantic Scholar, OpenCitations, Europe PMC, DataCite, NIH RePORTER, Wikipedia, Hacker News count of agreeing indices + orthogonal reach
VerifiabilityHow openly the result can be read, reused, and reproduced. Rewards open access, a permissive reuse license (CC-BY/CC0), a green repository copy anyone can archive, openly minable full text, and released datasets or software a reader can actually run. Cross-checked across OpenAlex, Unpaywall, Europe PMC, and DataCite.Maps to 0 to 100: Closed 45; open access 80+; a permissive CC license 100; a repository copy, open full text, or a released dataset/software artifact each raise the floor.Closed access450.209.0OpenAlex, Unpaywall, Europe PMC, DataCite is_oa / license / has_repository_copy / open datasets
IntegrityRetraction and post-publication correction status. A retracted result is not evidence of anything and collapses the whole Frontier Score; a correction or expression of concern is a softer flag. Read across OpenAlex and Crossref (both update-to and updated-by notices).Maps to 0 to 100: Clean 100; a correction or expression of concern 75; retracted 0. Flagged if OpenAlex OR Crossref records the notice.Correction / expression of concern on record750.2015.0OpenAlex, Crossref is_retracted / update-to / updated-by
Impact86
Impact sub-metrics
Sub-metricRaw value0 to 100WeightPointsSource
Field-normalized impactImpact relative to the world average for the same field, year, and type, so a small field and a large field are judged fairly. Triangulates three independent field-normalized measures: OpenAlex's Field-Weighted Citation Impact, its citation percentile within the exact field-and-year cohort, and the NIH iCite Relative Citation Ratio. 1.0x is average; the percentile is the share of same-field, same-year work it out-cites.Maps to 0 to 100: Each ratio (1.0 = field average) maps 1.0 to 50, 3.0 to 75, 9.0 to 90; the field+year percentile maps directly (top 1% -> ~99). The available measures are averaged. Falls back to a saturating citation count when none is available yet.104.1x FWCI, 40.6x RCR, top 0.0% of field-year vs field990.4544.5OpenAlex, NIH iCite fwci / citation_normalized_percentile / relative_citation_ratio
Influential citationsCitations that genuinely build on the work rather than mention it in passing (Semantic Scholar's influential-citation measure). A sharper signal of real impact than a raw count.Maps to 0 to 100: Saturating: 15 influential citations maps to 50. Falls back to a fraction of consensus citations when unavailable.10 influential400.208.0Semantic Scholar influentialCitationCount
Citation velocityCitations received in the trailing twelve months, judged as a rate rather than a lifetime total. Momentum is what a frontier index cares about: a result being taken up fast right now is landing, whether its lifetime pile is large or still small. Where an expected field citation rate is known, the momentum is also read relative to it, so a fast-moving result in a quiet field is not overlooked.Maps to 0 to 100: Saturating: 30 citations in the last twelve months maps to 50. When NIH iCite provides the field's expected rate, this is blended evenly with the ratio of observed to expected momentum.434 in last 12 months (48.9x field rate)960.3533.5OpenAlex, NIH iCite counts_by_year / field_citation_rate
Novelty48
Novelty sub-metrics
Sub-metricRaw value0 to 100WeightPointsSource
Conceptual noveltyHow genuinely new the contribution is, measured at publication from the work's OWN content, not its date: how atypical its combination of research areas is versus all prior work, and whether it builds on a broad, deep base rather than only the newest papers in a fast-moving area. This is what separates a real advance from a recent-but-commodity result, and it needs no forward citations, so it is stable for brand-new work. An honestly noisy proxy (even state-of-the-art novelty measures agree only moderately with expert judgment), so it carries bounded weight and never drives the ranking alone.Maps to 0 to 100: Blends two publication-time signals, each 0-100: an atypical-combination score (how unusual the pairing of the work's research topics is versus the prior literature, by pointwise mutual information) and a foundational-reach score (median age and depth of the work's references). The stronger signal weighs 0.62, the weaker 0.38. When neither is measurable (a work too thin in topics or references), the pillar renormalizes over its recency signals instead.Perovskite Materials and Applications x Thin-Film Transistor Technologies (913 prior works made this pairing); builds on refs a median 2.5y deep270.4512.2OpenAlex topics + referenced_works (publication-time)
RecencyHow recently the work appeared. The frontier is now, so newer scores higher.Maps to 0 to 100: Exponential decay with a 12-month half-life from the publication date.11 months old540.3016.1OpenAlex publication_date
Attention accelerationWhether attention is rising: citations in the latest full year versus the year before. Accelerating interest signals an active, opening frontier.Maps to 0 to 100: Latest/prior-year ratio: 1x maps to 50, 2x to 75, 4x to 100. Unknown is neutral.4.0x rising1000.1010.0OpenAlex counts_by_year
Edge of reviewPreprints and brand-new work sit ahead of the peer-review process. That earns novelty here (while it is discounted under Evidence), because it is where the frontier forms first.Maps to 0 to 100: Preprint 95, article <6 months 80, article <18 months 65, else 45.Peer-reviewed record650.159.8OpenAlex type / publication_date
ProvenanceAll sources

Sources and data

Every number behind this entry, grouped by the source that holds it: up to five citation indices cross-checked, field-normalized impact, then real-world reach (Wikipedia, community discussion, clinical trials, released data and public funding) where it exists. Each value links to its record.

OpenAlex

Primary record
Total citations
443
Field-weighted citation impact
104.1x field average
Citation percentile
Top 0.1% of its field-year
Citations, recent 12 months
434
Publication date
2025-11-06

Crossref

Citations
470
Works it builds on
45
Funders on record
3

Semantic Scholar

Citations, all versions
399
Influential citations
10

OpenCitations

Citations
54

Europe PMC

Citations
91

NIH iCite

Relative Citation Ratio
40.62x field average
Potential to translate
5%

Figures quoted in the write-up

FigureValueSource
certified steady-state power conversion efficiency27.2%Science
fraction of initial PCE retained after 1529 hours of MPPT under 1 Sun86.3%Science
duration of continuous maximum power point tracking under 1 Sun1529 hoursScience
fraction of original PCE an unpassivated device retained under MPPT at 85°C after 1000 hours82.8%Science
Materials & EnergyThe whole field

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