What it is
The work targets through-film inhomogeneity of chlorine, a factor the authors identify as limiting efficiency and stability, in formamidinium lead iodide films made with the common methylammonium chloride additive. Incorporating alkali metal oxalates, which thermally dissociate to release alkali metal cations that selectively bind chloride ions, homogenized the chlorine distribution, suppressed surface defects, and eliminated interfacial barriers. The resulting cells reached a certified steady-state power conversion efficiency of 27.2% and retained 86.3% of initial PCE after 1529 hours of continuous maximum power point tracking under 1 Sun.
Why it matters
Halide segregation in perovskite absorbers degrades both efficiency and operational lifetime, so controlling where chlorine sits through the film thickness addresses a mechanism, not just a symptom. The oxalate route couples a high certified efficiency with sustained stability, including an unpassivated device holding 82.8% of its original PCE under continuous operation at 85°C after 1000 hours.
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Filed underperovskite, solar cells, photovoltaics, thin films, power conversion efficiency