What it is
The authors develop a two-step route to make urea from ambient air and CO2. Plasma first activates ambient air into reactive nitrogen oxide species dominated by nitrite (92.1% NO2-), after which a single-atom Ru1/CuOx catalyst electrochemically co-reduces CO2 and those species to urea in a double-chamber membrane electrode assembly. The system reaches a urea yield rate of 106.9 mmol h-1 gcat-1 and a Faradaic efficiency of 86.7%, while avoiding the fossil-fuel-derived feedstocks that conventional electrochemical methods depend on.
Why it matters
Existing electrochemical routes to urea are held back by low conversion efficiency or dependence on fossil-fuel-derived nitrate feedstock. Drawing the nitrogen from ambient air through plasma activation and coupling it with CO2 addresses both constraints at once, pointing toward urea synthesis that does not rely on fossil feedstocks.
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Filed underAmmonia Synthesis and Nitrogen Reduction, CO2 Reduction Techniques and Catalysts, Catalytic Processes in Materials Science